How Are Essential Oils Extracted ?

Essential oils can be extracted via two key methods: Distillation (includes hydrodistillation) and Expression.

Absolutes, other the other hand, can be extracted via Solvent extraction or Enfleurage, although enfleurage is rarely performed in the modern day.

Another type of aromatic product available on the market are CO2 extracts, referred to simply as that, CO2 extracts. They differ in chemistry from their related distilled essential oils but are becoming increasing available on the market.

The Practice of Distillation

Distillation appears to have been practiced throughout ancient times. Based upon the current interpretation Paolo Rovesti’s discovery of an earthenware distillation apparatus, the production or extraction of aromatic oils by means of steam distillation, has been known for 5000 years.1 During the fifth century AD, the famed writer, Zosimus of Panopolis, refers to the distilling of a divine water and panacea. Throughout the early Middle Ages and beyond, a crude form of distillation was known and was used primarily to prepare floral waters or distilled aromatic waters. These appear to have been used in perfumery, as digestive tonics, in cooking, and for trading.

Although an extensive trade of odoriferous material has been shown to have occurred in the ancient Orient and ancient Greece and Rome, the oils used were not essential oils per se, “rather they were obtained by placing flowers, roots, and other plant material into a fatty oil of best quality, submitting the glass bottles containing these mixtures to the warming influence of the sun and finally separating odoriferous oil from the solid constituents”.

In 900 AD, Avicenna, the famous child prodigy from Persia who wrote many documents on plants and their uses and also instructions for massage, was accredited with refining the process of distillation by improving the cooling system.

Today distillation is still the most common process of extracting essential oils from plants. The advantage of distillation is that the volatile components can be distilled at temperatures lower than the boiling points of their individual constituents and are easily separated from the condensed water.

The Distillation Process

During distillation the plant material is placed upon a grid inside the still. Once inside, the still is sealed, and, depending upon the above methods, steam or water/steam slowly breaks through the plant material to remove its volatile constituents. These volatile constituents rise upward through a connecting pipe that leads them into a condenser. The condenser cools the rising vapour back into liquid form. The liquid is then collected in a vehicle below the condenser. Since water and essential oil do not mix, the essential oil will be found on the surface of the water where it is siphoned off. Occasionally an essential oil is heavier than water and is found on the bottom rather than the top, such as with clove essential oil.

The three types of distillation include:

Water Distillation
The plant material comes into direct contact with the water. This method is most often employed with flowers (rose and orange blossoms), as direct steam causes these flowers to clump together making it difficult for steam to pass through.

Water and Steam
This method can be employed with herb and leaf material. During this process, the water remains below the plant material, which has been placed on a grate while the steam is introduced from outside the main still (indirect steam).

Steam Distillation
This method is the most commonly used. During this process, steam is injected into the still, usually at slightly higher pressures and temperatures than the above two methods.

Note on Boiling Point: The boiling point represents the temperature at which a liquid is converted to a gas at a specified pressure. The fundamental nature of steam distillation is that it enables a compound or mixture of compounds to be distilled (and subsequently recovered) at a temperature substantially below that of the boiling point(s) of the individual constituent(s). Essential oils contain substances with boiling points up to 200°C or higher, including some that are solids at normal temperatures. In the presence of steam or boiling water, however, these substances are volatilized at a temperature close to 100°C at atmospheric pressure.

Percolation or Hydro-diffusion
This is a relatively recent method and is very similar to steam distillation except that the steam comes in through the top rather than the bottom, and there is a shorter distillation time. It is useful in extracting essential oils from woody or tough material or seeds such as fennel and dill.

Hydrosols: A By-product of Distillation
Hydrosols, also known as hydrolats, are the by-product or product (depending on the distiller purpose) of the distillation process. Hydrosols contain the water-soluble constituents of the aromatic plant and retain a small amount of essential oil. Every liter of hydrosol contains between 0.05 and 0.2 milliliter of dissolved essential oil, depending on the water solubility of the plant’s components and the distillation parameters.

*Please Note: The addition of essential oils to water is not at all the same as true hydrosols, and it is recommended that you read the ingredients label on products to ascertain whether or not you are getting a true hydrosol. When water and essential oils are mixed together with or without a dispersant, this is called a “spritzer” or “aromatic spritzer,” and this product should not be confused with a true hydrosol.